Catalytic Heterofunctionalization 2005 by A. Togni, H. Grützmacher

By A. Togni, H. Grützmacher

Show description

Read Online or Download Catalytic Heterofunctionalization 2005 PDF

Best nonfiction_3 books

SAT I (Cliffs Quick Review)

You recognize your SAT I ranking can determinewhich university or collage you attend,so why take an opportunity while getting ready for the examination? Written by means of top specialists within the box of try out practise, Cliffs speedy evaluate SAT I is helping you create an efficient learn plan so that you can meet your test-taking targets. The e-book explains the examination and descriptions the kinds of questions you come across; it additionally walks you thru an entire evaluate of the basic talents wanted in either the maths and the verbal sections.

The Cambridge Dover Wilson Shakespeare, Volume 27: The Poems

John Dover Wilson's New Shakespeare, released among 1921 and 1966, grew to become the vintage Cambridge variation of Shakespeare's performs and poems till the Eighties. The sequence, lengthy on account that out-of-print, is now reissued. every one paintings is obtainable either separately and as a collection, and every incorporates a long and vigorous creation, major textual content, and massive notes and thesaurus published on the again.

Catalytic Microreactors for Portable Power Generation

"Catalytic Microreactors for transportable strength new release” addresses an issue of excessive relevance and elevated complexity in power know-how. This thesis outlines an research into catalytic and gas-phase combustion features in channel-flow, platinum-coated microreactors. The emphasis of the learn is on microreactor/microturbine options for transportable energy new release and the fuels of curiosity are methane and propane.

Extra info for Catalytic Heterofunctionalization 2005

Sample text

Addition of silylborane (88) [137] and stannylborane (90) [138] to 1,3-dienes with a nickel(0) or palladium(0) complex affords analogous 1,4-addition products in high yields. 3 Metal-Catalyted Diboration, Silylboration and Stannylboration Pt(C2H4)(PPh3)2 octane, reflux Ph PhMe2SiO R + PhMe2Si-Bpin + RCHO R=Ph, 79% (syn/anti=99/1) R=C6H13, 71% (syn/anti=93/7) 88 Scheme 1-25 Pt Bpin SiMe2Ph SiMe2Ph pinB SiMe2Ph Pt Ph Pt RCHO pinB O Ph R Ph Scheme 1-35 106 Ph Bpin Allylation of Aldehydes nately not sufficiently regioselective and suffers from stereochemical isomerization, but the stannylboration yields a single product by selective migration of the boryl group to the less-substituted double bond.

Engl. 1998, 37, 1786-1801. (c) T. B. Marder, N. Norman, Topics in Catalysis, 1998, 5, 63-73. (d) G. J. Irvine, M. J. Lesley, T. B. Marder, N. C. Norman, C. R. Rice, E. G. Robins, W. R. Roper, G. R. Whittel, L. J. Wright, Chem. Rev. 1998, 98, 2685-2722. (e) L-B. Han, M. Tanaka, Chem. Commun. 1999, 395-402. (f) T. Ishiyama, N. Miyaura, J. Synthetic Organic Chemistry, Japan, 1999, 57, 503511. 3 Reviews for uncatalyzed hydroboration: (a) T. Onak, Organoborane Chemistry, Academic, New York, 1975. (b) B.

It is hoped that further innovative synthetic chemistry in diverse areas, stimulated by the metal-catalyzed methodology, will appear in the future. Abbreviations cod coe nbd dba Cy Py Cp Cp* 1,5-cyclooctadiene cyclooctene norbornadiene dibenzalacetone cyclohexyl pyridine η5-C5H5 η5-Me5C5 etpo TTMPP dppf dppm dppe dppp dppb P(OCH2)3CCH2CH3 tris(2,4,6-trimethoxyphenyl)phosphine, 1,1′-bis(diphenylphosphino)ferrocene Ph2PCH2PPh2 Ph2P(CH2)2PPh2 Ph2P(CH2)3PPh2 Ph2P(CH2)4PPh2 39 40 1 Hydroboration, Diboration, Silylboration and Stannylboration References 1 Reviews for catalyzed hydroboration, see: (a) L.

Download PDF sample

Rated 4.26 of 5 – based on 13 votes